A Highly Active, Thermally Robust Iron(iii)/potassium(i) Heterodinuclear Catalyst for Bio-Derived Epoxide/anhydride Ring-Opening Copolymerizations

Wilfred T. Diment,Gloria Rosetto, Noura Ezaz-Nikpay,Ryan W. F. Kerr,Charlotte K. Williams

GREEN CHEMISTRY（2023）

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摘要

A novel heterodinuclear Fe(iii)/K(i) catalyst is reported for the ring-opening copolymerization of epoxides and anhydrides, achieving turnover frequencies of up to 4800 h−1. It also shows activity for a broad range of bio-derived monomers.

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关键词

Homogeneous Catalysts,Heterogeneous Catalysts,Ring-Opening Polymerization

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