Resonance Raman spectroscopy characterization of linear carbon chains encapsulated by multi-walled carbon nanotubes

The unique electronic and vibrational properties of linear carbon chains (LCCs) have attracted close attention from the scientific community in recent years. Raman spectroscopy addressing the LCC spectral signature around 1850 cm−1 has been widely used to identify the LCC and probe electronic and vibrational properties as a function of carbon length. Despite the number of works available in literature, some aspects of the LCC's aforementioned properties remain unclear. Using a combination of confocal and Tip-enhanced Raman Spectroscopy (TERS), along with different laser lines, this work addresses important aspects of the optical resonance window of LCCs encapsulated by multi-walled carbon nanotubes (MWCNTs) (i.e. LCC@MWCNT) as well as an elusive Raman signature around 1637 cm−1, which is assigned to the LCC's longitudinal acoustic (LA) phonon mode at the X point (zone edge), which becomes Raman active likely due to disorder effects. First-principles calculations endorse our conclusions.