Common Origin of Trapped Volatiles in Oxidized Icy Moons and Comets

Following spacecraft encounters with comets 67P/C-G and 1P/Halley, it was surprising that O2, expected to be a very minor species in their comas, was observed to outgas at a few percent abundance during their ice sublimation phases. This challenged the direct connection suggested between comets and material in the interstellar medium (ISM), which exhibits a very low O2/H2O gas-phase abundance, leading to a number of papers suggesting novel sources for O2. Since these eccentrically orbiting comets have lost significant amounts of their evaporating surfaces over their lifetimes, the O2 observed must have been stably trapped down to significant depths in these primordial icy bodies. O2 was seen in the coma by Rosetta, along with other volatiles, long after water ice sublimation began to subside. Here we note that the extensive observations of the icy satellites of Jupiter (Europa, Ganymede, and Callisto) exhibit radiolytic and outgassing processes that provide certain direct parallels to interpretations of recent comet observations. Given that O2 is regularly observed in the atmospheres of icy Jovian satellites, as well as stably trapped as ‘bubbles’ (Johnson and Jesser, 1997) in their water ice surfaces, their spectral observations can help constrain the environment in which Jupiter-family and Oort cloud comets formed given that the observed O2/H2O abundances at both types of comets and icy moons are nearly identical. Based on the approximate charged particle radiation required to produce the observed steady-state concentrations of O2, we suggest that comets likely formed in a far more energetic environment than the ISM. While grains can be irradiated for longer timescales in the neutral ISM, small grains are expected to evaporate before significant O2 formation and trapping occurs. Independent of celestial dynamics then, an unknown radiation source, may provide insight to the first population of oxidized water ice grains in the early solar system.